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21.
22.
The two drill holes, which penetrated sub‐horizontal rare earth element (REE) ore units at the Nechalacho REE in the Proterozoic Thor Lake syenite, Canada, were studied in order to clarify the enrichment mechanism of the high‐field‐strength elements (HFSE: Zr, Nb and REE). The REE ore units occur in the albitized and potassic altered miaskitic syenite. Zircon is the most common REE mineral in the REE ore units, and is divided into five types as follows: Type‐1 zircon occurs as discrete grains in phlogopite, and has a chemical character similar to igneous zircon. Type‐2 zircon consists of a porous HREE‐rich core and LREE–Nb–F‐rich rim. Enrichment of F in the rim of type‐2 zircon suggests that F was related to the enrichment of HFSE. The core of type‐2 zircon is regarded to be magmatic and the rim to be hydrothermal in origin. Type‐3 zircon is characterized by euhedral to anhedral crystals, which occur in a complex intergrowth with REE fluorocarbonates. Type‐3 zircon has high REE, Nb and F contents. Type‐4 zircon consists of porous‐core and ‐rim, but their chemical compositions are similar to each other. This zircon is a subhedral crystal rimmed by fergusonite. Type‐5 zircon is characterized by smaller, porous and subhedral to anhedral crystals. The interstices between small zircon grains are filled by fergusonite. Type‐4 and type‐5 zircon grains have low REE, Nb and F contents. Type‐1 zircon is only included in one unit, which is less hydrothermally altered and mineralized. Type‐2 and type‐3 zircon grains mainly occur in the shallow units, while those of type‐4 and type‐5 are found in the deep units. The deep units have high HFSE contents and strongly altered mineral textures (type‐4 and type‐5) compared to the shallow units. Occurrences of these five types of zircon are different according to the depth and degree of the hydrothermal alteration by solutions rich in F and CO3, which permit a model for the evolution of the zircon crystallization in the Nechalacho REE deposit as follows: (i) type‐1 (discrete magmatic zircon) is formed in miaskitic syenite. (ii) LREE–Nb–F‐rich hydrothermal zircon formed around HREE‐rich magmatic zircon (type‐2). (iii) type‐3 zircon crystallized through the F and CO3‐rich hydrothermal alteration of type‐2 zircon which formed the complex intergrowth with REE fluorocarbonates; (iv) the CO3‐rich hydrothermal fluid corroded type‐3, forming REE–Nb‐poor zircon (type‐4). Niobium and REE were no longer stable in the zircon structure and crystallized as fergusonite around the REE–Nb‐leached zircon (type‐4); (v) type‐5 zircon is formed by the more CO3‐rich hydrothermal alteration of type‐4 zircon, suggested by the fact that type‐4 and type‐5 zircon grains are often included in ankerite. Type‐3 to type‐5 zircon grains at the Nechalacho REE deposit were continuously formed by leaching and/or dissolution of type‐2 zircon in the presence of F‐ and/or CO3‐rich hydrothermal fluid. These mineral associations indicate that three representative hydrothermal stages were present and related to HFSE enrichment in the Nechalacho REE deposit: (i) F‐rich hydrothermal stage caused the crystallization of REE–Nb‐rich zircon (type‐2 rim and type‐3), with abundant formation of phlogopite and fluorite; (ii) F‐ and CO3‐rich hydrothermal stage led to the replacement of a part of REE–Nb–F‐rich zircon by REE fluorocarbonate; and (iii) CO3‐rich hydrothermal stage resulted in crystallization of the REE–Nb–F‐poor zircon and fergusonite, with ankerite. REE and Nb in hydrothermal fluid at the Nechalacho REE deposit were finally concentrated into fergusonite by way of REE–Nb–F‐rich zircon in the hydrothermally altered units.  相似文献   
23.
The pressure dependence of the three lattice parameters and unit cell volume of fayalite (Fe2SiO4 olivine) was determined by X-ray diffraction under hydrostatic pressures up to 70 kbar. In order to eliminate stress inhomogeneity within a composite material consisting of a specimen mixed with an internal-pressure standard, a liquid (1 : 1 mixture of ethanol and methanol) was used as a pressure-transmitting medium. The isothermal bulk modulus calculated on the basis of the second-order Birch-Murnaghan equation of state gives the values K0 = 1.19 ± 0.10 Mbar and K0′ = 7 ± 4, and if we assume K0′ = 5: K0 = 1.24 ± 0.02 Mbar. Three axes of fayalite were found to be compressible in the following order, b >c >a. Comparisons with the results obtained under non-hydrostatic compression are made.  相似文献   
24.
Porphyroclastic diopside in garnet lherzolite from Alpe Arami, Bellinzona, Switzerland includes optically-visible clinoamphibole lamellae with a composition intermediate between pargasite and edenite. X-ray and electron microscopic observations show that the diopside crystal contains sub-microscopic thin clinoamphibole lamellae parallel to (010), which have coherent interfaces to the host. A kind of planar defect parallel to (010) in clinopyroxene structure, as suggested by Chisholm (1973), is shown here to correspond to intercalation of a 9 Å lattice fringe of double-chain structure in the electron micrograph of the diopside. The thin clinoamphibole lamellae are observed to be segregated domains consisting of two and more 9 Å fringes.From the chemical characteristics and textural relations of the development of such clinoamphiboles, the chemical change required to form them is considered to have been caused principally by decreasing solubility of atoms such as Na, Al and Cr in clinopyroxene structure during the retrogressive reequilibration. Also, a possibility of finite solid solution of clinoamphibole in clinopyroxene is discussed.  相似文献   
25.
During the 2000 activity of Miyake-jima volcano, Japan, we detected long period seismic signals with initial pulse widths of 1-2 s, accompanied by infrasonic pulses with almost the same pulse widths. The seismic signals were observed from 13 July 2000, a day before the second summit eruption. The occurrences of the seismic signals were intermittent with a gradual increase in their magnitudes and numbers building toward a significant explosive eruption on 18 August. After the eruption, the seismic and infrasonic events ceased. The results of a waveform inversion show that the initial motions were excited by an isotropic inflation source beneath the south edge of the caldera at a depth of 1.4 km. On the other hand, the sources of the infrasonic pulses were located in the summit caldera area. The times at which the infrasonic pulses were emitted at the surface were delayed by about 3 s from the origin times of the seismic events. It is suggested that small isotropic inflations excited seismic waves in the crust and simultaneously caused acoustic waves that traveled in the conduit and produced infrasonic pulses at the crater bottom. Considering the observed time differences and gas temperatures emitted from the vent, the conduit should have been filled with vapor mixed with SO2 gas and volcanic ash. The change of the time differences between the seismic and infrasonic signals suggests that the seismic source became shallower within half a day before the August 18 explosive eruption. We interpret the source process as a fragmentation process of magma in which gas bubbles burst and quickly released part of the pressure that had been sustained by the tensional strength of magma.  相似文献   
26.
27.
The eigen oscillation of a fluid sphere embedded in an infinite elastic medium is analyzed to understand the source mechanism of volcanic tremor that vibrates nearly monotonically and attenuates slowly. The dimensionless eigen frequencies of the sinusoidal oscillation are calculated in a complex form with the attenuation factor in its imaginary part for various combinations of the three parameters: the contrasts of P-wave velocity, density and rigidity between the fluid and the country rock. Eigen oscillations consist of a high attenuation mode with a rapidly decaying pulsive wave at a low frequency and infinite number of regular modes with slowly decaying vibrations. For regular modes, the frequency of oscillation obtained from the real part of an eigen value is distributed in approximately regular intervals while the attenuation factor from the imaginary part is almost constant independent of the mode. Each eigen frequency of regular and high attenuation modes is degenerated with two independent eigen functions describing different distributions of displacement, velocity and stress. The theory is applied to harmonic volcanic tremor observed at Kusatsu-Shirane Volcano, central Japan. Observed spectral peaks of the tremor are explained by the eigen frequencies and attenuation factors of several lowest regular modes if the spherical fluid oscillator has a radius of dozens of meters and a P-wave velocity of about several hundred meters per second.  相似文献   
28.
Abstract This paper contains extended abstracts of the seven papers presented at the symposium 'Radiolarians and Orogenic Belts' held at the seventh meeting of the International Association of Radiolarian Paleontologists (INTERRAD). Important results of the symposium include the following: (1) Upper Paleozoic and Mesozoic cherts are widely distributed within accretionary complexes in the circum-Pacific orogenic belt. Radiolarian dating reveals that long durations of chert sedimentation in a pelagic environment are recorded on both sides of Pacific-rim accretionary complexes (e.g. New Zealand, Japan, Russian Far East, Canadian Cordillera). (2) Triassic radiolarian faunas from New Zealand and the Omolon Massif, northeast Siberia are similar in composition and are characterized by the absence of typical Tethyan elements. This suggests that radiolarian faunal provincialism may have been established as early as the Triassic. High-latitude radiolarian taxa exhibit a bi-polar distribution pattern. (3) The Lower Triassic interval in chert dominant pelagic sequences is mechanically weaker than other levels and acted as a décollement in accretionary events. This lithologic. contrast in physical property is considered to reflect radiolarian evolution, such as the end-Permian mass extinction.  相似文献   
29.
A new technique has been developed for measuring the diffusion coefficient in ionic crystals. Based on Einstein's formula expressing the relation between diffusion coefficient and electric mobility, the electrical impedance of a diatomic ionic crystal is derived theoretically as a function of frequency of the applied electric field. In this method, the diffusion coefficients of both cations and anions are determined simultaneously by fitting the measured impedance to the theoretical relation. This method was applied to NaCl single crystals in the temperature range 370–780°C. The impedance was determined over the frequency range 0.01 Hz to 1 kHz, at constant temperature. The diffusion coefficients thus obtained for NaCl agree reasonably well with previous data by means of a radioactive isotope technique. The activation energies for Na+ and Cl? obtained are 1.97±0.03 eV and 2.08±0.06 eV, respectively, in the intrinsic region, and 0.92±0.02 eV and 1.06±0.02 eV in the extrinsic region. It was discovered that there are diffusion blocks of approximately 2 μm width, which obstruct free migration of ions in a single crystal.  相似文献   
30.
CS(J=1–0), C34S(J=1–0), and CH3OH(10–00A and E) emission lines in the core region of molecular cloud associated with NGC 7538 have been surveyed at angular resolution of 33. Distribution of CS column density shows two prominent peaks. Both blue and red wings in CS line are most prominent at 30 northwest of IRS 11.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.This work was carried out under the common use observation program at the Nobeyama Radio Observatory (NRO). NRO, a branch of the Tokyo Astronomical Observatory, University of Tokyo, is a cosmic radio observing facility open to outside users.  相似文献   
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